Stress enhancement in the delayed yielding of colloidal gels.
نویسندگان
چکیده
Networks of aggregated colloidal particles are solidlike and can sustain an applied shear stress while exhibiting little or no creep; however, ultimately they will catastrophically fail. We show that the time delay for this yielding decreases in two distinct exponential regimes with applied stress. This behavior is universal and found for a variety of colloidal gel systems. We present a bond-rupture model that quantitatively describes this behavior and highlights the role of mesoscopic structures. Our result gives new insight into the nature of yielding in these soft solid materials.
منابع مشابه
Colloidal gels under shear: Strain rate effects
Attractive colloidal particles are trapped in metastable states such as colloidal gels at high attraction strengths and attractive glasses and high volume fractions. Under shear such states flow via a two step yielding process that relates to bond and cluster or cage breaking. We discuss the way the structural properties and related stress response are affected by the shear rate. At low rates c...
متن کاملIntroducing nanostructure patterns for performance enhancement in PbS colloidal quantum dot solar cells
With attention to the thin film structure of colloidal quantum dot solar cells, in this paper in order to improvement of active layer absorption of them, we have proposed the use of nanostructure pattern for enhancement of their performance. For this purpose we have presented suitable nano hemisphare patterns in colloidal quantum dot solar cells for light trapping in absorption layer. Then with...
متن کاملPolar-molecules-driven enhanced colloidal electrostatic interactions and their applications in achieving high active electrorheological materials
We have fabricated a class of colloidal electrorheological (ER) fluids, in which suspended TiO2 particles were synthesized by a sol-gel method and modified by 1,4-butyrolactone molecules with a permanent molecular dipole moment of 4.524 D. Compared with pure TiO2 ER fluids, the quasi-static yield stress of the polarmolecules-modified ER fluid is enhanced as high as 48.1 kPa when subjected to an...
متن کاملTimescales in creep and yielding of attractive gels.
The stress-induced yielding scenario of colloidal gels is investigated under rough boundary conditions by means of rheometry coupled with local velocity measurements. Under an applied shear stress σ, the fluidization of gels made of attractive carbon black particles dispersed in a mineral oil is shown to involve a previously unreported shear rate response γ dot above(t) characterized by two wel...
متن کاملYielding of colloidal gels under steady and oscillatory shear
Submitted for the MAR15 Meeting of The American Physical Society Yielding of colloidal gels under steady and oscillatory shear GEORGE PETEKIDIS, ESMAEEL MOGHIMI, NICK KOUMAKIS, IESLFORTH, FORTH TEAM — The structural and rheological properties of intermediate volume fraction colloid polymer gels are examined during and after steady and oscillatory shear flow using rheometry, confocal microscopy,...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Physical review letters
دوره 106 24 شماره
صفحات -
تاریخ انتشار 2011